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No best answer has yet been selected by Snappy. Once a best answer has been selected, it will be shown here.
For more on marking an answer as the "Best Answer", please visit our FAQ.Tinned peaches must surely be cooked, or they'd go off in the tin. The whole principle of tinning and bottling is to cook to death then seal out the air while still boiling.
But anyway, it's an easy test to make: cook fresh peach, taste. Who's got a fresh peach about the place?
Casey - nectarines are just varieties of peach which do not have the fuzz, so there is no consistent difference once the skin is off.
Another possibility is that different varieties are used for tinning.
Personally I much prefer fresh ones, if properly ripe -- I find tinned ones rather slimy (but why should that put me off? I like snails, pickled mushrooms and lots of other slimy things).