Turn all your rad thermostats up to full. If the noise stops then you know it's the 'stats restricting the flow of water. 'Stats used to be one-way, some are now 2 way, if your 'stats were fitted the wrong way then the noise would be instantaneous. After you've checked your 'stats call a plumber. Additives to the system,a, lubricate the pump,b,inhibit corrosion in the boiler and rads (not pipes),c, act as anti-freeze,d, have a bubble effect so if there is a leak you can see the liquid bubbling out. The amount of initial corrosion (in fact never) in copper pipes is zero, the builders were spinning a yarn