you may be lucky if the gate valves work in the air cupboard, one pipe should defo go to the base of the hot cylinder that controls the cold top up from this tank in the loft, and thence you get hot water out of the top, this cyl never empties itself, care should be exercised when trying to close these gate valves they have a nasty habit of sticking the wedge gate shut then later to open, the spindle disengages,and a new valve is needed ,also any other valve in the air cupboard may be heating valves defo leave alone.
If you are as terence says unlucky then you will need to turn the mains off usually under the sink if you can't locate then you may need to go round inside the property to find the stop **** if you turn that off then run hot and cold taps in the lowest part then eventually the loft tank only and pipe work will be emptied and work can begin on the taps and as paddywak advises fit service valves, they are the ones with screw drive slots,to prevent accidental turning,
hth Tez