a possible problem is pipework layout, which may not be the answer in this case as presumably the system worked ok before or a blockage in the pipework causing it to send the water up the vent pipework. do you have a cylinder in the airing cupboard? if so get one of your fridge magnets and see if the magnet will stick to the pipework that feeds off the F&E tank above in the loft, where it joins the pipework that tees from this feed ,the pump pipework and the c/h pipework.the magnet wont stick usually but if the pipe is sludged up with crap/hard scale then the magnet will stick.a quick test to try.
if it sticks then its a drain down, cut out the blocked pipwork and replace