It all depends on what you mean by 'paint.' If you intend to have an oil based finish in, say, matt or eggshell, then I would recommend an oil based plaster primer - after allowing the plaster to dry out for a week or two. If, as is more likely for ceilings, you wish to finish in emulsion paint then first apply a coat of emulsion thinned with an equal measure of cold water to act as a sealer ( reduces suction/absorbtion) followed by two or three coats of your chosen emulsion finish.or you can buy a special plaster sealer which makes following coatings easier to apply less like trying to paint a sponge ! Good luck.