I have a Worcester combi boiler & since engineer gave it its annual service last week the central heating comes on when the hot tap is turned on! Have checked timer settings
Sounds like the diverted valve sticking.I have a very old Valiant boilet that nwas doing the same about 12 years ago, I just moved it with a heavy screw driver the sprayed a little wd 40 no trouble since. But I don't know your boiler my diverter I think is hydraulic not electic but if I am wrong I stand corrected.