A better solution than polystyrene would be poylurethane foil backed boards, but again you would have to cut them to size and vapour seal to prevent cold bridges. Having said this, you would also have to capor seal the mineral wool for the same reason, however, polyurethane has a far better insulation value than mineral wool.
Another option would be to use 2 component polyurethane spray on foam. It is the same material as the polyurethane boards, except you spray it on.
This website has an interesting comparison chart of various insulation materials:
http://www.spray-insulation.co.uk/Insulation_m aterial_comparison.htm