This is right on the limit.
No real worries about then repair, so long as it is done properly; but 79.5 psi = 5.48 bar.
Few automotive pressure gauges are that accurate. You runthe risk of under-inflation (will generate too much heat), or over-inflation (may over-stress the reinforcement in the tyre, especially at high speeds)
Your main enemy here is heat. If you are running at 60mph/100kph and not on roads that are excessively hot (Italian Autostrada del sol), then it *should* be OK.
But wow, that's close to the limit.
Your margin of safety will depend a bit on how many tyres are supporting that weight; how much load you're carrying, what speed and the temperature of the air and the asphalt/concrete.
Personally, I'd be looking for maybe bigger tyres. I'd definitely want them to have a high load rating (the number (such as 103) after the designation 227/75R16 S (or whatever speed rating) - and the XL rating.
Are these the recommended fitment from the manufacturer?