ok, so you have the nice thing to remember,
soh/cah/toa
this stands for sine (opposite/hypotenuse) / cosine (adjacent/hypotenuse) / tan(opposite/adjacent)
sine(angle) = opposite / hypotenuse
cosine(angle) = adjacent / hypotenuse
tan(angle) = opposite / adjacent
each one of these three things, soh, cah or toa, has theee parts to it -- each has an angle, and two lengths of the triangle. regardless of whether you're trying to work out an angle or a length, you must always have two of these things to be able to work out the third. so, all this really boils down to it figuring out what two things you have, and what third thing you are trying to find!
for example, if you are trying to calculate the angle in a triangle and have the opposite and hypotenuse lengths of that triangle, then you'd use sine. why? because the sine equation i've written above has three parts: an angle, the opposite side length, and the hypotenuse side length. so, you have two of these, and are trying to find the third. now, to actually do the calculation, put in the numbers you have. for example, you may have the opposite side being of length 1, and the hypotenuse side being of length 2. so, the equation would be
sine(angle) = 1/2 = 0.5
so, you know that the sine of the angle is 0.5. but, you're wanting the angle, obviously! to do this, you actually divide by sine on both sides of the equation, to get
angle = sine^-1 0.5
the ^-1 means sine to the power -1, which is the same as meaning divide by sine. usually you have to press shift sine on your calculator, and it'll show sin-1 or similar. just type sin-1 0.5, and press equals, and it'll tell you what the angle is.