1. There is a "health in Pregnancy" grant of £190 - not means tested.
2. Child benefit - £20 p wk for the first child - is not means tested.
3. SMP is paid for 39 weeks - the first 6 wks at (I think) 90% of gross pay, & the rest at a flat rate of a bit over £100 p wk. This assumes you do not have a better entitlement from your employment contract.
4. If you give up work the family income will decrease & you may find you are entitled to Child Tax Credit. This is means tested but can be paid (at a low rate) up to gross family income of £50,000 pa +. If you return to work & need paid for child care (with registered or approved child minders) a substantial % of the cost can be included in the Tax Credit.
5. If you do have an entitlement to Tax Credits it is possible you may also be eligible for a one off "Surestart" maternity grant of £500.