They can only meet on multiples of days that are a product of the periodicity of each visit. They meet every (2 x 3) days, i.e. every 6 days:
1. M B
2. _ _
3. M _
4. _ B
5. M _
6. _ _
7.M B
The only way they can meet twice in the first week is if they meet on the 1st and the 7th days. They next meet on the 13th, then the 19th, then the 25th. So they meet 6 times during the 28 days.
Being pedantic however, this assumes that they both arrive at the same time each day.