She can certainly transfer the money to that effect. She's not liable for the debts of her husband.But if you are thinking that the state or NHS will pay anything you should, unfortunately, forget it, unless he has very little money in capital (from memory, when my mother went into one the figure was no more than �25K.It may be less.).That's not the case here. What's more, methinks it unlikely that your mother will refuse to pay if the �100,000 is running out.