If you'll be living in the UK for most of the year, and operating a business from here, you'll be a UK taxpayer and not a US one. (Your nationality is irrelevant).
IRS form W-9 only refers to a business-contractor relationship which is subject to US taxation, so it doesn't apply to you.
IRS form 8233 only applies to non-US citizens in the USA, who are seeking exemption from certain taxes. So, since you're outside the US tax system anyway, that also doesn't apply.
IRS form W8-BEN has to be submitted to any company that would normally be obliged to deduct US taxes from payments if it's necessary to show that the person completing the form isn't subject to US taxation. So that appears to be the one you need.
However I need to add a caveat to the foregoing. If you're going to declare that your business is UK-based you'll need to register with HMRC for self-assessment and to declare the nature of the business which you're running. I think it's likely that you can't do that without a National Insurance number and you can't get one unless you've currently got the right to work here. So if your student visa prohibits you from taking up employment in the UK you could have a problem.