From what I can see in TV listings, the show is not repeated during the week. However (and I know it's not quite the same...), you can watch the interview on Youtube. It is on in 3 parts - here are the links:
I find the accent very cute. Being Northern Irish, I also have an accent as thick as a tea-cosy. And the way he blushed when he was talking about K. Knightly having to '**** him off'. Eeeeeh....!