Yes, there are 8x8 = 64 cells in the grid, but only 8x6 = 48 are occupied by the digits 1 to 6 (eight of each). There are also seven 7s, six 8s and three 9s. So there are exactly enough cells to make eight cube nets, with only one possible layout.
To get started finding the nets I suggest you start in the cell numbered 37. Check which of the three adjacent cells could be part of the same net, and shade the two cells the same colour. Then repeat the process for the other three cells around the second cell, but this time just note the possibilities, as you could go down the wrong track. However, it soon becomes apparent that there is only one way to obtain six contiguous cells with different digits.
Then repeat the process with a different colour ....