I know this one is "extremely difficult", but I'm still curious to see how we arrive at the answers, so any help will be much appreciated!
http://www.crossword.org.uk/work.htm ACROSS:
24:Special shop instruction involving Tyneside that coud be catching ( 8 ):S???????
DOWN:
21.Insert again - about the twentieth attempt? ( 7 ): ????ANT
22. Servants surprisingly ignoring very silky tissue ( 7) : ????NE?
23. Disgrace, terrible, no good, it's the drink! ( 7 ) :????CA?
26. Rodent, American, I drag up ( 5 ): A????
27. rarely command return of performance(it's dropped)
R????
30. Former ruler of France and Austria(4):?F?A
31. In the manner of Lavoisier's final chemical spray ( disused ) ( 4 )?L?R