One site states "...The final coating -- the release -- emphasizes an interesting distinction in the world of stickiness: adhesion versus cohesion. In adhesion, one type of molecule is sticking to another type of molecule; in cohesion, one type of molecule is sticking to itself. Tape uses both [source: Scientific American]. The molecules of the adhesive stick to the molecules of the substrate, or adhere, but they also stick to each other, or cohere. If this weren't the case, the adhesive substance wouldn't hold together. The release coating prevents cohesion at the surface of the tape so it can be unrolled easily..."
By the way, one of the most useful products in my shop is WD-40 ... meant as a lubricant, it will clean up the Duct Tape residure, clean ones hands after working in an oily, dirty environment, etc.
Additionally re: Duct Tape... ever twist off a light bulb from its metal base when removing it? After assuring the light fixture is isolated from electricity at the circuit breaker or fuse box, wad a small amount of duct tape into a ball small enough to be pushed into the broken fixture's base with enough left over to hold onto. Just twist it out as you would normally... works great every time...