The answer, contrary to intuition, is: ONE-THIRD.
Considering all possible two-children families, the second child has a probability one-half of being the same sex as the first. Therefore half of all two-children families are the same sex (B+B or G+G), and half of them are one of each (B+G or G+B). Note especially that the three possibilities (GG, BB, and BG) are NOT equally likely.
Mr Smith's family are not (G+G), and the case in question (B+B) constitutes one-third of the remaining equally likely cases.