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No best answer has yet been selected by HugoP. Once a best answer has been selected, it will be shown here.
For more on marking an answer as the "Best Answer", please visit our FAQ.Water begins to expand when the temperature falls below 4 degrees Celcius and upon freezing to ice, its volume is about 9% greater than liquid water.
I believe this property of expansion on freezing is unique to water.
It also has a number of other strange or unexpected properties. Its melting and boiling points are considerably higher than would be expected when compared to other compounds with similar properties.
It also has a relatively high specific heat value which makes the oceans a useful "battery" for storing the energy given out by the Sun. The sea (or indeed rivers and lakes) take considerably longer to heat up and cool down than the land does, and this has a profound effect on the Earth's climate.
All in all, handy stuff!
Apparently, both gallium and bismuth are less dense in their solid form than in their liquid forms.
http://encarta.msn.com/encyclopedia_761571486_2/Liquid.html
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