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To enrich Uranium in the sort of quantities necessary either for weapons or for a reasonable reactor you need to create Uranium Hexafloride gas.
Most early pioneers working with pure flourine met somewhat early deaths.
The issue is that there's great technological boundary to making a crude uranium bomb like the Hiroshima one if you can enrich uranium enough for a power station you can enrich it enough for a bomb.
Making an atomic bomb is relatively easy - getting theenriched uranium is really hard
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