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Microwave Ovens
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For more on marking an answer as the "Best Answer", please visit our FAQ.microwave ovens produces waves with a frequency that is only marginally different from the resonant frequency of water - this means that the water molecules vibrate like crazy, so gets hotter, which is conducted through all the other molecules and so the food gets hot.
plates don't contain an awful lot of water
I regularily heat plates in the microwave. Even though I understand that microwaves work by vibrating water molecules, they do heat up plates.
I also have a small plastic bowl, that gets preposterously hot when heated in the microwave even for a short time. I've never understood why when plastic contains no water.
Sorry I'm a bit late with this answer, been having trouble posting answers on the new format site.
If you use your microwave with no food in it you run the risk of permanently damaging the Magnatron (device which creates the microwaves). The microwave is really designed for heating-up foodstuffs and you should not use for the heating of tableware alone. As others have said, I always leave a bowl of water in mine in case I switch it on accidentally. An empty microwave is a dangerous place when switched-on.
Hope this belated answer helps.
While heating up food in a microwave, I've noticed that some plates get really hot fast while others don't heat up as quickly. So some property of the plate affects the way it reacts in the microwave. I know some glazes used on ceramics contain metals and I know that you are not supposed to put metal in the microwave. Could this be the cause?