Some numbers are intrinsically more important than others. Prime numbers are a well known example.
There are even more special numbers such as the Heegner Numbers:
1, 2, 3, 7, 11, 19, 43, 67, 163
http://en.wikipedia.org/wiki/Heegner_number
Expressions based on these numbers lead to outcomes that are not intuitively expected even though most of them have been fully explained with a mathematical justification.
Almost integer expressions are quite interesting.
http://en.wikipedia.org/wiki/Almost_integer
My favourite almost integer is e^(pi* sqrt(163)).