We had double glazing fitted throughout the house in 2004 (wedding present from my parents). About a year later a pane in the main bedroom "exploded" in exactly the way you describe, except it was the inside pane. Had I not been in the house at the time and known for a fact there was nobody in the room in question and it was the internal pane that went, I'd have sworn something had hit it. It was a crack like it had been hit and it had a pattern like it came to a central focus point.
I called the firm that fitted the windows who came round and had a look. They in turn contacted the manufacturer who confirmed they'd had a number of problems with a batch of windows manufactured at that time whereby the pressure wasn't exactly correct in the vacuum between panes and in some cases they eventually simply imploded (technically they cracked inwards, not outwards). They replaced the window free of charge of course and warned it was possibly that any of the others manufactured at the same time might also go. A couple of months later one in the other bedroom did the same thing and was also replaced free of charge.
We've had no problem with them at all in the five years or so since. None of the others ever went.
So, can it happen without anything striking the window? Yes, definitely, I've seen it happen. Insurance? No idea, we didn't need to. If the windows are relatively new and the firm who put them in still exist I'd ask them for comments first. If not, I'd be surprised if property insurance doesn't cover it but it may cost less than your excess to just get it replaced.