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Thank you both. I downloaded DVDFAB and decrypted the film. I then searched for it on the HDD and after a bit of fiddling around selecting folders in the browse pane, managed to get DVD Shrink to open it in the preview pane. From there everything went as normal - I didn't even need a Dual Layer disc to copy it to.
I suppose it was the ideal candidate to test the ability of DVDFAB as it was a Sony film with their encryption method in place. The film by the way was Black Dawn with Steven Seagal.
Thank you both again