http://www.apple.com/osx/how-to-upgrade/
"If you are running Lion (10.7.x), you’re ready to update to Mountain Lion. Go to Step 3. If you are running Snow Leopard (10.6.x), update to the latest version of OS X Snow Leopard before you purchase OS X Mountain Lion from the Mac App Store. Click the Apple icon and choose Software Update to install Snow Leopard v10.6.8, the latest version."