I'm with gen2 on this one:
A card is taken out and placed face up on the table showing a red face ... so you can ignore the white/white card .... so basically the puzzle now boils down to:
There are 2 cards, one red/red, the other red/white. I will now remove a card and place a red side facing up - what are the odds that the other side is also red ??
First impressions are it's 50/50 but look again ....
When the red side is revealed, we do not know whether it is the red side of the red/white, or if it's side 1 of the red/red, or side 2 of the red/red. Clearly, there are 3 different red sides that you can pick. If side 1 of the red/red is showing, or side 2 of the red/red is showing, then obviously the other side will be red (2 in 3 chance). If the red side of the red/white is showing, then the other side will be white (1 in 3 chance).
An even simpler explanation:
3 cards in a bag:
red/white: R/W
red/red: R1/R2
white/white: W1/W2
Each side is labelled accordingly and you now proceed to pull one card out, look at one face, note its face and replace it back in the bag and continue for say 6000 results.
All things being equal, the results will be (or close to):
R - 1000 observations
W - 1000
R1 - 1000
R2 - 1000
W1 - 1000
W2 - 1000
This is in a purely random case, which also includes results for white being the noted colour. We want to discard white results, so we now see results as
R - 1000
R1 - 1000
R2 - 1000
i.e. for every 3000 times a red side is seen, the red side of the red/white card will be seen 1000 times (1 in 3 times) and the other 2 sides of the red/red card will be seen 200 times (2 in 3 times).