just to clarify a little.
Printers use colour subtraction for making other colours, the primary colours used for this are normally cyan, magenta and yellow. using colour subtraction it is impossible to make white. imagine you had a pot of cyan paint, one of magenta and one of yellow. try and think of what possible way you could mix those paints to make white. it's impossible and if you mix all three you will get black.
Explained why and how here
http://www.ux1.eiu.edu/~cfadd/1160/Ch23RR/Sub. html
the other method of mixing colours is colour addition, this deals with the mixiing of coloured lights. the normal primary colours for this are red, green and blue. with colour addition then if you mix all three coloured lights you get white light.
this should explain colour addition a bit more, and the two little animations right at the bottom show the difference in results of mixing colours using either subtraction (ink) or addition (light)