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I have trvs, my neighbour doesn't (I have suggested he think about getting some, if only for the lounge), so don't know why his rads got so hot. It was all so much simpler before I moved, with a wireless thermostat, & on mains gas - being on calor now (& just ordered new bottles yesterday), I'm much more aware of how much I'm using.
As for positions of rads, I'm not changing those ! LOL I've 4 in the lounge, but the windows all pretty much go to the floor (French doors, picture windows, side window) so they're more opposite windows rather than under, though 3 are by internal doors. The thermostat's in the hall, opposite the front door, so I've just left internal doors open. Once I'd turned the boiler temp up it did get very warm in here so did turn the thermostat down ! This seems to be the "norm" in these park homes - have heating on for a short time & the heat is just retained, which I'm not used to having moved from a house where I basically had the heating on quite low but all the time.