The Rolling Stones used the Robert Moog synthesiser on Satisfaction in the 1960s.
You might wish to define "technology" more precisely....
Many bands in past two decades used phone lines to transfer data in recording songs -- sure, old hat now but exciting when they first did it. I am thinking of Buffy Sainte Marie doing "The Big Ones Get Away" in such a way. U2 and Johnny Cash exchanged their duet The Wanderer in such a way.
Above all, I'd consider the Beatles for the use of live satellite when first performing "All You Need Is Love" in 1967. We really knew then that the universe had no boundaries. See site below.
http://en.wikipedia.org/wiki/All_You_Need_Is_L ove