Now while that single sperm has been crossing the zona pellucida, changes have been occuring in zona pellucida itself. Granular substances are formed rapidly as a result of the action of enzymes released by the egg and the sperm. Other substances in the zona pellucida play a part too. The result is rapid formation of granular material in the zona pellucida. These granular substances coalesce turning the entire zona pellucida into the biological equivalent of cement.
By this time, our sperm will have joined with the egg. All the same his mates won't be far behind and may even have started their journey through the zona pellucida. When the layer is solidified, they are trapped, can proceed no further. and usually die. The other sperm that have not reached the zona pellucida find that they can't penetrate it and they normally die too.
It's because of this solidification, that only one sperm can join with one egg. So what could happen if two or more sperm could join with the egg? Well, polyspermy as it's known never occurs in nature. Laboratory studies have shown incontrovertibly that polyspermy leads to the death of the majority of embryos within days. Embryonic survival following polyspermy is completely unknown in mammalian species. The hardening of the zona pellucida is a simple, yet ingenious method of preventing polyspermy thus guaranteeing the survival of the species.