I can't think of a book which would specifically help you but it would be useful if you learnt to burn files and folders to a CD without using Picasa. Instructions will be in the book you've already got or you can find them here:
http://www.microsoft.com/windowsxp/using/setup /expert/bridgman_august13.mspx
Programs like Picasa don't store pictures within the actual program itself. The files exist in a folder on your hard drive (e.g. in 'My Pictures' or in a folder you've created yourself). Picasa simply accesses the files in that folder. (If you're not sure where your pictures are stored, run a search for *.jpg, which will show you where they are).
Once you know where your pictures are stored you can organise them (without recourse to Picasa) into folders such as 'Holiday 2008', 'Fred's Family', etc). You can then burn those folders directly onto a CD, using XP's burning software, which automatically defaults to creating a multi-session disk.
Chris
PS: Picasa is a good program but, for greater flexibility in manipulating your images, I recommend this free download:
http://www.freeserifsoftware.com/software/Phot oPlus/key_features.asp