beso, the amount of silica in tree ash is hardly measurable. It's often not in the range of parts per thousand let alone the "few percent" you assert.
The white ash left behind from burnt trees is mainly composed of Calcium no matter what climate the trees are located in. Ash from trees that have grown in sandy soil, do indeed show a slightly higher amount of silica in the ash due to deposition of silica in bark, but the increase is negligible.
Have a look at the following link for further information:
http://forestry.oxfordjournals.org/cgi/reprint /79/5/563.pdf