buildersmate's answer is correct but it applies to any diode, including semiconductors.
A thermionic diode has a glowing filament which either emits electrons in its own right or, more usually, heats a more efficient emitter of electrons known as the cathode.
These electrons are captured by a metal plate - the anode - which is at a positive potential compared with the cathode. This gives rise to a current flow across the vacuum that exists between the two electrodes.
It is a one-way action - the positive anode collects negative electrons. There is no way that the action can work in reverse.