ok XP or previous
Click Start > Control Panel > Network Connections >
Right click 'Local Area Connection' and select properties
Highlight 'Internet Protocol(TCP/IP) and select properties.
if 'Use the following IP Address' is checked then its likley that both computers have the same IP address (ie: 192.168.123.100), hence your message,
simply change the last set of 3 numbers to something else, (making sure that no one else has used this address)
you can first check if it isnt already on the network, by
clicking start > run > type cmd, click ok and type ping (your new ip address that you want to use)