10a City left in danger, sort of - 9 letters 24a Angry words about a king and a book - 4 letters 22d bloke - white back and face - 4 letters 7d Third-rate, like hard bread - 4 letters
7d is cash. third is +as(like) + h(hard) bread is slang for cash.
10a is leningrad. anag. of in danger + L(left)
22d is sid(bloke) + e(last letter of white) =side (face)
24a is rant. R(king) + a + NT(book)