As the water heats in your system it expands. Since it's a 'closed system' there has to be somewhere for the extra water to go. So your boiler has in it an 'expansion vessel'. This is a cylindrical tank divided in two internally by a rubber diaphragm, with water from the system on one side, and air under a bit of pressure on the other side. If you're really sure that your system has no leaks anywhere else, it's quite possible that there could be a leak in the rubber diaphragm, and that's allowing the water to escape. It's not an uncommon occurrence, and if this is what's happening, the only answer is to have the expansion vessel replaced.