jomifl, I double-checked the "'cools a bit by the time it reaches the zones" and I think i was wrong: I was feeling the rads.. but the piping itself (both flow and return) are too hot to touch for more than 1 second.
I've taken a photo of the where the 22mm piping becomes lots of 12mm..
https://picasaweb.goo...g#5679684060598344754
The column on the right is the flow, the column on the left is the return. Below those two, below the taps, there is a T junction going to the second zone. (I guess).
Only 2 rads are turned on. All of the 12mm piping off the right column (flow) are too hot to touch more than 1sec. All of the 12mm piping off the return columnn, are also too hot to touch apart from one near the top.
(I presume these are heating up by convection).
The valve that is attached to the left hand column is connected to the thermostat. Does this valve open/close both the flow and return? to the right of the valve you can see a white cap - this can be unscrewed but I am not sure what it does.
I'm not sure that any of this helps narrow down causes?
is the airlock scenario still a possible cause?
Thanks!
Melvin