Hello Supermike
vascop and HowardKennitby are absolutely correct. Here's a little more for you with a bit of maths:
You would need a current of about 1 ampere in a 1/10th second pulse (much less current for a sustained electric shock) passing through your body to stop your heart.
If we assume that your body has an electrical resistance of say, two hundred and forty ohms, and that is only a guess, then according to the formula: voltage = current multiplied by resistance, 240 volts will be lethal (240 volts = 1 ampere x 240 ohms), however it depends upon the time that the current is available from the voltage source. Obviously, 240 happens to be the voltage of the mains in the UK, so that's why the mains which can supply a current indefinitely can kill you.
We all encounter tens of thousands of volts every day from objects all around us in the form of static electricity, such as by taking off a pullover or brushing our hair but the current is only available for thousandths of a second as there is so little energy available and therefore we are not killed by it. The only result is a slight prickling sensation or we may hear a crackling sound. Lightning is a form of static electricity, but it kills people because the clouds it discharges from are so huge that they can supply a large sustained current through the strike. If your pullover were a mile square, then taking it off would probably be fatal!
So in a nutshell high voltage from say, the mains will certainly kill you so don't risk contact with it. High voltage static electricity from your pullover is safe as it cannot supply a sustained high current.
Regards
Peter Jameson