Sheffield Children's Hospital C/D...
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For more on marking an answer as the "Best Answer", please visit our FAQ.The CGT rules can be complex, but if you live on the second home as your main residence for a time before selling it you will not be liable for CGT for the period you do so. You may be liable for the period up to the date it becomes your main residence so you should get a valuation at the date you move in. If the house is currently in joint names and is changed into your sole name it is possible a CGT liability may crystallise at that point if you make the change after the divorce, but I think it would be a joint liability with your ex-husband.
Have a trawl through HMRC website CGT section, which may have more specific info. It is best not to take a chance, so you may need a solicitor or accountant to advise you.