Times, 26,064

[red46]

3d, S?r?i??, Nervous type, with shrew initially for wife, is more pitiful.
14a, 2words, 7.6. ????I?n ?e?i?n, Relief going on manoeuvres in force.
14d, ??u?t?a?e, Inhibit initially fast oxidation speed.

[Lie-in King]

3d Sorrier - from 'worrier' (nervous type), change 'w(ife)' for 's(hrew)' (initially)
14a Foreign Legion - anag 'relief going on'
14d Frustrate (inhibit) - 'f(ast)' + 'rust' (oxidation) + 'rate' (speed)

[samak]

14d frustrate

[red46]

Thanks, lie-in king for your help.

[red46]

And samak.