I wash at night and shower in the morning. I don't find baths at all relaxing. I wouldn't feel at all fresh and clean for the day if I didn't have a morning shower and I don't think I am sweaty and smelly when I go to bed!!
It depends what I have got planned for the day. When I was at work, I showered before going to work and maybe again when i got home (some people's homes were definitely not sanitary!)
Now I am retired, if my day is going to be spent in clean pursuits, I may well shower first thing but if I am planning to do DIY or garden or work around the house then I will shower at the end of the day.