Seeking answers for the following with parsing if possible, please!
32a Hardly the headgear that's worn around work(7, hyphened):
??????A
42a A blushing leaseholder (13, two words): ?????ER??????
4d A rocket from the head(5): O????
6d Apparently a noblewoman, brave, topless and unable to hear(7):
E?????S ( EMPRESS ?)
10d Copper enters rebuilt tool-room causing eyes to swivel(10):
O?????????