5d) any precious corundum gemstone that is not red, especially the highly valued transparent blue variety (8)
22d) an ornament worn round the neck (7)
"THANKYOU"!!!!!!!!!
36a - very thin and bony : scraggy 14d - to order someone to do something ; urge strongly 3d - a decree, order or ordinance issued by a sovereign, state or other holder of authority thankyou!!!