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I often hiccup when I eat certain very hot foods. Nothing to do with gulping air or large quantities; I will often hiccup with just the first forkful of a chili pickle, say. It's not a serious problem, and in some ways I rather enjoy the experience, not least because it is controllable, and a little drinking washes away the tendency after a minute or so.
Then again, I don't hiccup when I drink a lot of alcohol. dipsomaniacs are stereotypically portrayed as hiccuppers, aren't they? So perhaps I an unusual. I presume the heat of the chili pepper is stimulating the reflex in some way directly in the throat. It happens very quickly after eating something hot -- sometimes within a minute - so it's probably not something absorbed in the bloodstream and working on the brain, but locally.