Sorry to see that you're in trouble again, bb. Plenty of good advice given already.
Most pressure relief valves will operate around 3 or 3.5 bar. 5 bar is unusual. Your "dribble in the alley" is, from a safety point of view, a good thing. However, at 5 bar, I would expect more of a flow (as has already been pointed out.)
Possibly, the relief valve is faulty, not opening fully.
so, maybe faulty valve or a flow sensor somewhere.
Also possibly, there's a leak in the heat exchanger which is over-pressurising the system.
More likely though, is that pressure vessel has lost its air pressure somehow (usually a ruptured diaphragm.) The pressure vessel is a small tank that accepts normal water expansion as the temperature of the system rises. If this expansion vessel fails (it may just need pumping up), then water expands too much and is thrown out of the system.
Reducing pressure somehow may well bring the pressure down to the right level........... but, as the system cools (when the heating goes off), the pressure may not be enough to restart. (Usually around 0.5 bar.)
So, no help, I'm afraid. Too many ifs and buts. Until Monday, keep an eye on the pressure. That's all you can do.
My bet? ............ you need pumping up, bb. Boiler guys just use a car foot pump usually.