The TRV might be stuck closed. You should be able to remove the thermostatic head, possibly by unscrewing a knurled 'lock ring' where the head meets the valve. If it comes off, you should see a small metal pin in ther centre of the exposed bit of valve; this pin should be sticking up from the valve - if it is not then it is probably stuck down. If possible you might be able to grab the tiny bit of pin with pliers and give it a gentle tug to fre it and make it then possible to pushh down with the plier end and see if it then pops back up, if so then all should be well when you replace the head. By the way, once freed it will probably allow the radiator to get hot rather quickly, which makes replacing the head a bit dodgy on your fingers.
If the pin can't be pulled, then try pushing it down with a small implement like a screwdriver or use a nail as a punch and give it a tap. This might free it.
It may be wise to leave the heating off until the TRV is back in place, to avoid hot fingers. Good luck.
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