Hi, I dont have an answer for you but I know exactly what you are going through and how frustrating and expensive it is. I have a Vaillant Boiler, I am not sure how old as it was in when we moved in 3 yars ago but since the day we moved in we have had a similiar problem and always around the coldest time of year.
It starts by the pilot light going out for no reason however you just relight it and it works for a couple of days. then it does it again and you relight etc etc. Then it stays lit whislt central heating is on for about 3 hours before clicking off, but as soon as hot water goes on and it fires up the pilot light goes out. I use to dread putting the water on as you heard the click when it happened.
I am currently going through it again at the moment. We use to be with british gas and they struggled, it has had new thermo couples, mag valve, and more (not sure of spelling) and once it starts every engineer struggles to stop this problem. I have not had one person out yet who has said , ah this is the problem, they have simply changed everything on it and it has worked for few months and then started again.
I am sick of paying out money and getting nowhere. This is why I just thought I would search the web and see if anybody had any advice. Really struggling. I have had no central heating and hot water for over a week now. Had 3 different guys out cost me each time but still not fixed. Dont really want to go down route of new boiler when ahve just paid out �300+ in engeering fees to be no wiser. At least before engineers came out I had central heating every 3 hours, now they cannot get it lit at all for more than 5 minutes before just clicking off. They are saying that the flame is not high enough to touch thermo couple but there is no valve to allow more or less gas through etc.
Any suggestions?