you say you've disconnected the filling loop already so two other possibilities:
firstly, the expansion vessel needs re-pressurising, a quick and simple job for a heating engineer. basically the expansion vessel is half full of water and half full of air, the 2 sides being seperated by a diaphragm. the air side is pressurised to about 0.5 - 0.7 bar, the chances are your expansion vessel has lost its air and it needs re-filling. it is very rare for an expansion vessel to actually fail, but the heating engineer can test for this by pressing in the car tyre type valve on the expansion vessel and if water comes out of what should be the air side then the diaphagm has failed and you need a new expansion vessel fitted.
the other option is there is a leak in the water to water heat exchanger (secondary heat exchanger ) and the mains water is leaking into the heating circuit. again quite rare but we did actually have this exact fault on a worcester only last week.
my money would be on your expansion vessel needing repressurising, i would repair this for �50 and include a service on the boiler for that, we do tend to be cheaper than most people though, were in birminhgam if your in that area.