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Yipee!!! I found out what was causing the smell - one of our daughters is a hairdresser and had dumped some used hair products in the little bathroom bin!
Fortunately I've been really busy doing some major projects in the garden before I go back to work, otherwise I would have been ripping panelling off days ago!
Obviously there was some ammonia in there but there must have been some other stuff that had gone bad, when I opened the bin it really stank so I didn't even dare to try and find out what it was! I never even thought to look near the bin, I've been concentrating on the toilet area, thank goodness it was bin day yesterday!
Thanks everyone!