Hi, If and when you top up your system the eccess water should flow out of your overflow pipe which is attached to your Header tank, Start the car up as said and check the underside of the car for the water, Is the car running ok apart from that? Is the car Sluggish? Water in the derv!! Have you run the car HOT?? If so Head Gasket, You best bet is to get the car Coolant pressure tested as said not by an agent but a Decent Garage not a rip off dealer, To test the system should cost in the region of about �20 that is good i comparison to a dealer Good Luck.